The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Halogenated N-compounds(inorg) / ClNO2 / JPL-2015(2015)_210-296K_200-475nm(rec)

DATAFILE: ClNO2_JPL-2015(2015)_210-296K_200-475nm(rec).txt
NAME: nitryl chloride
FORMULA: ClNO2
AUTHOR(YEAR): JPL-2015(2015)
T: 210-296K
λ: 200-475nm(rec)
BIBLIOGRAPHY: J. B. Burkholder, S. P. Sander, J. Abbatt, J. R. Barker, R. E. Huie, C. E. Kolb, M. J. Kurylo, V. L. Orkin, D. M. Wilmouth, and P. H. Wine, "Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 18", JPL Publication 15-10, Jet Propulsion Laboratory, Pasadena, 2015 http://jpldataeval.jpl.nasa.gov
COMMENTS: JPL-2015(2015) recommendation: The recommended absorption cross sections are taken from

B. Ghosh, D.K. Papanastasiou, R.K. Talukdar, J.M. Roberts, and J.B. Burkholder, "Nitryl chloride (ClNO2): UV/Vis absorption spectrum between 210 and 296 K and O(3P) quantum yield at 193 and 248 nm", J. Phys. Chem. A 116, 5796-5805 (2012); DOI: 10.1021/jp207389y

at 5-nm intervals and rounded to 3 significant figures

The recommended temperature coefficients A and B for the parameterized temperature dependence of the absorption spectrum

σ(λ,𝑇)= σ(λ,296 K) × [1+𝐴(λ) × (T−296) + 𝐵(λ) × (T−296)2]

are listed in columns 3 and 4

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